Unusual Violet Maxixe Beryl

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This 26.72 ct Maxixe beryl has an unusual violet color.

Figure 1. This 26.72 ct Maxixe beryl has an unusual violet color. Photo by Diego Sanchez.

Recently examined in the Carlsbad laboratory was a 26.72 ct transparent violet modified cushion mixed-cut stone (figure 1). Standard gemological testing revealed a refractive index of 1.583–1.592 and a specific gravity of 2.78, both consistent with beryl. Using plane-polarized light, pale purple and saturated blue pleochroic colors were observed. A uniaxial optic figure was seen at the girdle, and the optical orientation of the stone showed the stronger blue pleochroic color down the optic axis direction. The stone was inert to long-wave UV light and fluoresced weak greenish yellow to short-wave UV. Viewed with fiber-optic light during microscopic examination, it displayed a few scattered blocky crystals, platelets, and needles, confirming natural growth origin. No coatings were seen on the surface under reflective light. Other than the unusual violet color, these properties were consistent with Maxixe beryl.

UV-Vis-NIR spectra for the e- and o-rays show the pleochroic colors in the Maxixe beryl.
Figure 2. The violet beryl showed a typical UV-Vis-NIR spectrum for Maxixe beryl. Pleochroic colors were calculated from the spectra and revealed a blue (o-ray, dark blue trace and color swatch) and light vio­let (e-ray, pale purple trace and color swatch) pleochroism.

Advanced testing by LA-ICP-MS revealed that the stone lacked iron. This result was consistent with Maxixe beryl, in which iron is too low to be measured (I. Adamo et al., “Aquamarine, Maxixe-type beryl, and hydrothermal synthetic blue beryl: Analysis and identification,” Fall 2008 G&G, pp. 214–226). Maxixe beryl normally has a blue to violet blue bodycolor, but this stone showed an unusual violet color. The UV-Vis-NIR spectrum (figure 2) showed absorption bands between 500 and 700 nm and a broad band near ~690 nm. This spectrum was consistent with Maxixe beryl (again, see Adamo et al., 2008). While Maxixe beryl has been found to be colored by natural irradiation, it can also be produced by artificial irradiation. Some of these “Maxixe-type” beryls produced by artificial irradiation are known to fade when exposed to “mild heat or strong light” (see Winter 1997 Lab Notes, p. 293). However, there is no conclusive test to determine whether Maxixe color results from natural or artificial irradiation, and as such, beryl in the blue to violet color range that shows the type of visible spectrum previously mentioned is designated simply as the Maxixe variety of beryl by the GIA laboratory.

Spectra of the Maxixe beryl during a fade test.
Figure 3. From the violet beryl material provided for this study, a wafer was fabricated in order to directly measure the absorption spectra while conducting a fade test by placing the sample four inches away from an intense 150-watt halogen light source. The results, normalized to a 25 mm path length, confirmed that the color became less saturated over time with exposure to light. Most of the color loss came from the o-ray direction (left).
Color swatches generated from the polarized visible spectra collected during the fade test.
Figure 4. The polarized visible spectra were used to produce color swatches of the ordinary-ray (E ⊥ c) and extra­ordinary-ray (E || c) color normalized to a 25 mm path length to illustrate the change in color during fade testing over a period of 32 hours at four-hour intervals.

A small sample cut from the same rough as the 26.72 ct violet beryl was provided by lapidary Nolan Sponsler for destructive testing in order to evaluate the color stability of this material. An optically oriented wafer, 4.45 mm thick and normalized to a 25 mm path length in order to better observe the change in color, was fabricated from this sample with parallel polished windows that are parallel to the optic axis to allow measurement of the o- and e-rays. UV-Vis-NIR spectra were collected on the sample prior to fade testing and at four-hour intervals of exposure to a 150-watt halogen bulb at a distance of approximately four inches from the bulb to avoid any significant heating (figure 3). The results showed fading of the sample until its color was very pale (figure 4), confirming that this material may fade. One should avoid prolonged exposure to light and store it in a dark environment to preserve the color.

This violet Maxixe beryl was purported to be from Santa Maria de Itabira, Minas Gerais, Brazil. It is notable for its unusual color and its fantasy cut design. In addition to this violet Maxixe beryl, another violet beryl group mineral named “johnkoivulaite” was documented in 2019 (see Fall 2019 GNI, pp. 454–455); that new beryl is from the Mogok mining area in Myanmar. However, standard gemological properties clearly separate the two violet beryl minerals. Even though this beryl owes its appealing violet hue to what would be considered an unstable color center, the color should remain intact if prolonged exposure to intense light sources is minimized.

Source: gia.edu Amy Cooper, Ziyin Sun, Dylan Hand, and Nathan Renfro

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